N-(Benzothiazol-2-yl)-3-chlorobenzamide
نویسندگان
چکیده
The title mol-ecule, C(14)H(9)ClN(2)OS, exists in the solid state in its amide form with a typical C=O bond length, as well as shortened C-N bonds. The plane containing the HNCO atoms subtends dihedral angles of 12.3 (4) and 8.1 (3)° with the planes of the phenyl ring and benzothia-zole group, respectively, whereas the dihedral angle between the planes of the phenyl ring and the benzothia-zole group is 5.96 (6)°. In the crystal, mol-ecules form inter-molecular N-H⋯N hydrogen bonds, generating independent scissor-like R(2) (2)(8) dimers.
منابع مشابه
{μ-2-[(Benzothiazol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxyphenolato-1:2κ3 O 1,O 6:O 1}{2-[(benzothiazol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxyphenolato-1κO 1}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia-zol-2-yl)hydrazonometh-yl]-6-methoxy-phenol ligands, a methanol mol-ecule and a nitrate ion. Both Cu(II) centres are penta-coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N-H⋯O and O-H⋯O hydrogen bonds.
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The asymmetric unit of the title compound, C(16)H(14)ClN(3)OS, contains two independent mol-ecules (A and B) linked into dimers via N-H⋯N hydrogen bonds. The 1,3-benzothia-zol-2-yl ring system and the benzene ring form dihedral angles of 17.08 (8) and 8.63 (7)° in mol-ecules A and B, respectively.
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In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and weak O-H⋯O inter-actions, f...
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In the title compound, C(15)H(17)N(3)OS(3)·H(2)O, the piperidine ring has a chair conformation. The crystal structure is stabilized by weak inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen-bonding inter-actions.
متن کامل2-[(1,3-Benzothiazol-2-yl)iminomethyl]-4-bromophenol
In the title compound, C(14)H(9)BrN(2)OS, the dihedral angle between the benzene rings is 3.1 (3)°. An intra-molecular O-H⋯N(imine) hydrogen bond occurs. The crystal structure is stabilized by weak inter-molecular C-H⋯O inter-actions.
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